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Massachusetts Estuary Project(MEP) <br /> Linked Watershed Embayment Model PeerRevieiv_ <br /> including storinwater generation from transportation(roads,parking lots),roof and <br /> other runoff-generating areas was completed to estimate stormwater volumes,with <br /> concentrations estimated from standard sources. <br /> While individual parcel,road and other land cover estimates of nitrogen input to the watershed and <br /> recharge to groundwater will be uncertain,averaging over the number of parcels and total impervious <br /> areas in each groundwater catchment area provides the total and mean application and recharge rates <br /> required for this analysis. These means and totals are more stable and have less uncertainty than <br /> individual parcels(based on the law of large numbers) and are the required information for loading <br /> magnitude and delivery patterns to the estuaries. Moreover,independent measurements of groundwater <br /> loads by Kroeger et al. (1999,2006)and Valiela et al. (2000)for Green Pond approximately match the <br /> MEP estimates,building confidence that the MEP results are reasonable. <br /> Key Issue 3—Uncertainty and Sensitivity Analysis <br /> Sensitivity analysis evaluates the effects of changes in input values,parameter estimates,assumptions and <br /> algorithms on a model's results. Uncertainty analysis investigates the effects of lack of knowledge and <br /> other potential sources of error in the model,and when conducted in combination with sensitivity <br /> analysis, allows a model user to be adequately informed about the confidence that can be placed in the <br /> model results. U.S.EPA(2009)recormnends sensitivity analysis as the principal evaluation tool for <br /> characterizing the most and least important sources of uncertainty in environmental models. <br /> There are numerous and varied inputs to the load estimates as discussed above(e.g. septic nitrogen <br /> concentrations,fertilizer leaching rates, groundwater recharge rates, etc.). Further, some important <br /> contributing processes are captured with only one-or two-digit accuracy—for example,50%o of the <br /> nitrogen transported through each of the major freshwater ponds is assumed to be attenuated. These low- <br /> accuracy inputs imply that nitrogen load estimates with five-digit accuracy,as included in the MEP <br /> reports,are impossible. The uncertainty in these inputs also implies that there are margins of uncertainty <br /> around the resulting load estimates. While the Panel does not recommend any wholesale changes in the <br /> approach to estimating nitrogen loads to the bays and estuaries at this stage,we recommend changes in <br /> the presentation of MEP results so as to acknowledge explicitly that there is uncertainty in the load <br /> estimates and to provide some estimate of the degree of uncertainty. <br /> The Panel further recornmends that model sensitivity analyses be conducted for nitrogen mass loads for <br /> each specific estuary. A healthy recognition that there is uncertainty would encourage planning bodies to <br /> pursue an adaptive monitoring and management strategy as they move forward to understand and remedy <br /> the impacts of nitrogen on bays and estuaries. Such an adaptive strategy is wise in light of the <br /> uncertainties in predicting the response of bays and estuaries to future load reductions. <br /> Key Issue 4—Nitrogen Attenuation in Groundwater <br /> The SMAST Team assumes there is no attenuation of nitrogen in groundwater,which they appropriately <br /> indicate to be a conservative approach(Howes et al. 2002). While this is a reasonable and conservative <br /> assumption,there is ample information in the technical literature to show that nitrate(NO3)from septic <br /> systems is almost certainly converted to nitrogen gas(N2)by bacterially-mediated denitrification in the <br /> subsurface,but the extent varies widely. Denitrification occurs by a microbially mediated stepwise <br /> chemical reaction as follows: <br /> NO3-—NO2-—NO—>N20-->N2 <br /> Anaerobic conditions and a substrate to support microbial populations(typically carbon)are needed for <br /> denitrification and most denitrification occurs in the vadose zone in the near vicinity of septic system <br /> leaching fields and subsurface wastewater discharges. In saturated groundwater, the extent of <br /> denitrification is highly variable and depends primarily on the availability of dissolved organic carbon <br /> (DOC)(Pabich et al. 2001). Kinetic models for denitrification indicate that the reaction proceeds quickly <br /> _.�� December 30,2011 <br />